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Catalytic upgrading of lactic acid to fuels and chemicals by dehydration/hydrogenation and C-C coupling reactions

Autores

SERRANO RUIZ, JUAN CARLOS, Dumesic, James A.

Publicación externa

Si

Medio

Green Chem.

Alcance

Article

Naturaleza

Científica

Cuartil JCR

1

Cuartil SJR

1

Impacto JCR

5.836

Impacto SJR

2.088

Fecha de publicacion

01/01/2009

ISI

000268747700002

Abstract

Aqueous solutions of lactic acid can be catalytically processed over Pt(0.1%)/Nb(2)O(5) into a spontaneously-separating organic layer that can serve as source of valuable chemicals (propanoic acid and C(4)-C(7) ketones) and/or can be used to produce high energy-density liquid fuels (C(4)-C(7) alcohols). The niobia support plays a key role in the synthesis by catalyzing dehydration and C-C coupling reactions.

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