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Elucidating the structure of amorphous-carbon films containing carbide and non-carbide-forming metals

Authors

ENDRINO ARMENTEROS, JOSÉ LUIS

External publication

No

Means

J. Electron Spectrosc. Relat. Phenom.

Scope

Article

Nature

Científica

JCR Quartile

SJR Quartile

Publication date

01/12/2024

ISI

001358730600001

Scopus Id

2-s2.0-85208768644

Abstract

This work makes a first comparison of the structural features of the amorphous carbon matrix in a-C:Mo and a-C: Au films deposited using the pulsed filter cathodic arc technique. The present study combines synchrotron X-ray absorption (XAS) and emission (XES) in conjunction with transmission electron microscopy observations and selective area diffraction (SADP). While diffraction techniques can be used to indicate the formation of crystalline particles for the metal phase, and transmission electron microscope (TEM) images can be used to indicate the clustering and formation of metallic nanoparticles, the collection of X-ray absorption (XAS) and X-ray emission (XES) spectra is a valuable approach to elucidate the electronic structure of the surrounding amorphous carbon phase and interpret their physical properties.

Keywords

XANES; XES; Diamond-like carbon; Composite coatings

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