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Catalytic upgrading of lactic acid to fuels and chemicals by dehydration/hydrogenation and C-C coupling reactions

Autores

SERRANO RUIZ, JUAN CARLOS, Dumesic, James A.

Publicación externa

Si

Medio

Green Chem.

Alcance

Article

Naturaleza

Científica

Cuartil JCR

Cuartil SJR

Impacto JCR

5.836

Impacto SJR

2.088

Fecha de publicacion

01/01/2009

ISI

000268747700002

Abstract

Aqueous solutions of lactic acid can be catalytically processed over Pt(0.1%)/Nb(2)O(5) into a spontaneously-separating organic layer that can serve as source of valuable chemicals (propanoic acid and C(4)-C(7) ketones) and/or can be used to produce high energy-density liquid fuels (C(4)-C(7) alcohols). The niobia support plays a key role in the synthesis by catalyzing dehydration and C-C coupling reactions.