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Catalytic upgrading of lactic acid to fuels and chemicals by dehydration/hydrogenation and C-C coupling reactions

Authors

SERRANO RUIZ, JUAN CARLOS, Dumesic, James A.

External publication

Si

Means

Green Chem.

Scope

Article

Nature

Científica

JCR Quartile

SJR Quartile

JCR Impact

5.836

SJR Impact

2.088

Publication date

01/01/2009

ISI

000268747700002

Abstract

Aqueous solutions of lactic acid can be catalytically processed over Pt(0.1%)/Nb(2)O(5) into a spontaneously-separating organic layer that can serve as source of valuable chemicals (propanoic acid and C(4)-C(7) ketones) and/or can be used to produce high energy-density liquid fuels (C(4)-C(7) alcohols). The niobia support plays a key role in the synthesis by catalyzing dehydration and C-C coupling reactions.