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Commercial Grade of P(3HB-co-3HHX) Final Properties Adjustment by the Modification of Cooling Conditions in the Injection Molding and Ageing Process

Autores

IVORRA MARTINEZ, JUAN, Gomez-Caturla, Jaume , Peydro, Miguel Angel , Selles, Miguel Angel , Boronat, Teodomiro

Publicación externa

No

Medio

Macromol. Mater. Eng.

Alcance

Article

Naturaleza

Científica

Cuartil JCR

2

Cuartil SJR

1

Impacto JCR

4.6

Fecha de publicacion

01/06/2024

ISI

001181089000001

Abstract

Poly(3-hydroxybutyrate-co-3-hydroxyhexanoate) is a polymer obtained by bacterial fermentation that emerges as an alternative to polymers of petrochemical origin. The complex crystallization kinetics that occurs over 15 days after melting, known as ageing, limits its industrial application. During the aging process, there is a change of the degree of crystallinity, which has an effect on the chemical structure of the material. Additionally, changes in the mechanical properties, colorimetry, and dimensional shrinkage are observed. Different material properties are observed depending on the cooling conditions employed. For the ageing process, two different conditions are considered: ageing at room temperature and annealing at high temperature (60 degrees C).

Palabras clave

ageing and annealing; degree of crystallinity; injection molding; mechanical properties; P(3HB-co-3HHx); PHA

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