Título Large-scale oxygen-enriched air (OEA) production from polymeric membranes for partial oxycombustion processes
Autores GARCÍA LUNA, SEBASTIAN, ORTIZ DOMÍNGUEZ, CARLOS, Chacartegui R. , Pérez-Maqueda L.A.
Publicación externa No
Medio Energy
Alcance Article
Naturaleza Científica
Cuartil JCR 1
Cuartil SJR 1
Web https://www.scopus.com/inward/record.uri?eid=2-s2.0-85146569855&doi=10.1016%2fj.energy.2023.126697&partnerID=40&md5=31339bc490602c4ffe5f2accfaff4738
Fecha de publicacion 16/01/2023
ISI 929075500001
Scopus Id 2-s2.0-85146569855
DOI 10.1016/j.energy.2023.126697
Abstract Partial oxycombustion using Oxygen-Enriched Air (OEA), produced by air-gas separation with polymeric membranes, combined synergistically with CO2 capture technologies, can reduce the overall energy cost of CO2 capture, and it is a potential alternative to conventional CO2 capture technologies. An exhaustive review of polymeric membranes for this application is presented. The best membranes showed permeability values in the 450–25,100 barrer and selectivities higher than 3.6 for large-scale operations. These membranes can produce OEA with oxygen molar concentrations of up to 40% for retrofitting large-scale power plants (~ 500 MWe) with partial oxycombustion. For OEA production, the polymeric membrane system is more efficient than cryogenic distillation since the specific power consumption of the former is 35.17 kWh/ton OEA. In comparison, that of the latter is 49.57 kWh/ton OEA. This work proposes that the OEA produced by the membranes feed a partial oxycombustion process integrated with calcium looping within a hybrid CO2 capture system. The power consumption of the hybrid CO2 capture system proposed here is 29.05% lower than in the case OEA is produced from cryogenic distillation, which justifies the potential interest in using polymeric membranes for OEA production. © 2023 Elsevier Ltd
Palabras clave Calcium; Cryogenics; Distillation; Electric power utilization; Energy efficiency; Gas permeable membranes; Molar ratio; Oxygen; Polymeric membranes; Calcium looping; Capture system; CO2 capture; Cryog
Miembros de la Universidad Loyola

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