Gomez, Virginia , Balu, Alina Mariana , SERRANO RUIZ, JUAN CARLOS, Irusta, Silvia , Dionysiou, Dionysios D. , Luque, Rafael , Santamaria, Jesus
Si
Appl. Catal. A-Gen.
Article
Científica
3.41
1.573
28/10/2012
000308733200006
Nd-doped titania materials prepared using a mild microwave-assisted protocol have been found to possess excelling activities in the photodegradation of water contaminants including phenol and Rhodamine B. These materials were characterized by a number of techniques including N-2 adsorption, X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), and X-ray photoelectron spectroscopy (XPS). The prepared materials showed high surface area, with the highest value for the catalyst containing a Nd/Ti ratio of 0.03 (341 m(2)/g). The dopant agent was found to be as Nd3+ ions located on the surface and in the inter-planar space of titanium oxide crystals. Effects of the surface area together with the Nd content and the adsorption ability of the material seem to be involved in the optimum photocatalytic activity found for 0.5%Nd (Nd0.005/TiO2) and 6%Nd (Nd0.06/TiO2) containing materials. (C) 2012 Elsevier B.V. All rights reserved.
Neodymium; Titania; Photocatalysis; Phenols; Band gap; Water treatment