Título Simulation of the thermogravimetry analysis of three non-wood pulps
Autores Garcia Barneto, Agustin , CARMONA CARMONA, JOSÉ ALBERTO, Martin Alfonso, Jose E. , Sanchez Serrano, Rafael
Publicación externa Si
Medio Bioresour. Technol.
Alcance Article
Naturaleza Científica
Cuartil JCR 1
Cuartil SJR 1
Impacto JCR 4.365
Impacto SJR 2.089
Fecha de publicacion 01/05/2010
ISI 000274972600044
DOI 10.1016/j.biortech.2009.12.034
Abstract In a study of three non-wood pulps (rice straw, EFB, and Hesperaloe), the standard pyrolysis model for biomass based on hemicellulose, cellulose, and lignin pseudo-components, was modified to include char volatilization. As a result, abnormally high values for lignin content have been avoided. On the other hand, the consideration of autocatalysis (Prout-Tompkins equation) for TGA data simulation under inert and oxidative atmospheres, allows obtaining a stable set of kinetic parameters that describe volatilization and char oxidation for different heating rates, including char ignition. These simulations allow us to investigate certain effects like oxygen influence on cellulose-char formation (including reduction in activation energy) and to calculate the composition of samples. (C) 2009 Elsevier Ltd. All rights reserved.
Palabras clave Pulp; Thermogravimetry analysis; Pyrolysis; Combustion; Kinetic study
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