| Title | Efficient Room-Temperature O-Silylation of Alcohols Using a SBA-15-Supported Cobalt(II) Nanocatalyst |
|---|---|
| Authors | Rajabi, Fatemeh , Luque, Rafael , SERRANO RUIZ, JUAN CARLOS |
| External publication | Si |
| Means | Chem. Biodivers. |
| Scope | Article |
| Nature | Científica |
| JCR Quartile | 2 |
| SJR Quartile | 2 |
| JCR Impact | 1.808 |
| SJR Impact | 0.611 |
| Publication date | 01/09/2012 |
| ISI | 000308715800016 |
| DOI | 10.1002/cbdv.201200071 |
| Abstract | The O-silylation of OH groups of alcohols and phenols with hexamethyldisilazane (HMDS) was achieved in high-to-excellent yields using catalytic quantities of a SBA-15-supported cobalt(II) nanocatalyst (typically 0.5 mol-%) at room temperature and under solvent-free conditions. Furthermore, the heterogeneous catalyst showed an excellent durability and can be conveniently reused by filtration for at least twelve times without any noticeable loss of activity. |
| Keywords | Silylation; SBA-15; Cobalt catalyst; Nanocatalyst; Alcohol protection; Catalysis |
| Universidad Loyola members |