Title Mixed-Valence Ce/Zr Metal-Organic Frameworks: Controlling the Oxidation State of Cerium in One-Pot Synthesis Approach
Authors Ronda-Lloret, Maria , Pellicer-Carreno, Isaac , Grau-Atienza, Aida , Boada, Roberto , Diaz-Moreno, Sofia , Narciso-Romero, Javier , SERRANO RUIZ, JUAN CARLOS, Sepulveda-Escribano, Antonio , Ramos-Fernandez, Enrique V.
External publication No
Means Adv. Funct. Mater.
Scope Article
Nature Científica
JCR Quartile 1
SJR Quartile 1
JCR Impact 19.92400
SJR Impact 5.00000
Web https://www.scopus.com/inward/record.uri?eid=2-s2.0-85105134866&doi=10.1002%2fadfm.202102582&partnerID=40&md5=2e16bcfacfd4363e576306dab6dbb20c
Publication date 01/07/2021
ISI 000647480700001
Scopus Id 2-s2.0-85105134866
DOI 10.1002/adfm.202102582
Abstract The preparation of MOFs including a metal with an easily exchangeable oxidation state, while maintaining the same crystal structure and stability, is of paramount importance for myriad applications. In this work, a new synthesis method is reported that can be used to prepare Ce/Zr-MOFs (UiO-66 structure) having only Ce(III), a mixed-valence Ce(IV)/Ce(III), or only Ce(IV) cations, as desired. The materials are characterized using a large number of techniques, including X-ray absorption and X-ray photoelectron spectroscopies.
Keywords metal organic frameworks; mixed‐ valance; one‐ pot synthesis; X‐ ray adsorption
Universidad Loyola members

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