Title A Conceptual Approach for the Design of New Catalysts for Ammonia Synthesis: A Metal—Support Interactions Review
Authors ARROYO CAIRE, JAVIER, DIAZ PEREZ, MANUEL ANTONIO, LARA ANGULO, MAYRA ANABEL, SERRANO RUIZ, JUAN CARLOS
External publication No
Means Nanomaterials (Basel)
Scope Review
Nature Científica
JCR Quartile 1
SJR Quartile 1
Publication date 01/01/2023
ISI 001115372300001
DOI 10.3390/nano13222914
Abstract The growing interest in green ammonia production has spurred the development of new catalysts with the potential to carry out the Haber–Bosch process under mild pressure and temperature conditions. While there is a wide experimental background on new catalysts involving transition metals, supports and additives, the fundamentals behind ammonia synthesis performance on these catalysts remained partially unsolved. Here, we review the most important works developed to date and analyze the traditional catalysts for ammonia synthesis, as well as the influence of the electron transfer properties of the so-called 3rd-generation catalysts. Finally, the importance of metal–support interactions is highlighted as an effective pathway for the design of new materials with potential to carry out ammonia synthesis at low temperatures and pressures. © 2023 by the authors.
Keywords 3rd-generation catalysts; electron transfer; green ammonia; mild conditions
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