| Title |
Interplay of Support Chemistry and Reaction Conditions on Copper Catalyzed Methanol Steam Reforming |
| Authors |
DIAZ PEREZ, MANUEL ANTONIO, Moya, Javier , SERRANO RUIZ, JUAN CARLOS, Faria, Jimmy |
| External publication |
No |
| Means |
Ind Eng Chem Res |
| Scope |
Article |
| Nature |
Científica |
| JCR Quartile |
1 |
| SJR Quartile |
1 |
| JCR Impact |
3.37500 |
| Web |
https://www.scopus.com/inward/record.uri?eid=2-s2.0-85056796345&doi=10.1021%2facs.iecr.8b02488&partnerID=40&md5=61d23ac822f73e2e315e775667c66b56 |
| Publication date |
14/11/2018 |
| ISI |
000451101900006 |
| Scopus Id |
2-s2.0-85056796345 |
| DOI |
10.1021/acs.iecr.8b02488 |
| Abstract |
A series of Cu catalysts supported on SiO2, Al2O3-SiO2, TiO2 rutile, and\n Cu/TiO2 anatase metal oxides has been studied for methanol reforming in\n the vapor phase. The highest activity was obtained on Cu/SiO2 catalysts\n (5493 mu mol H-2 min(-1).g(cat)(-1)) followed by Cu/TiO2 rutile,\n Cu/Al2O3-SiO2, and anatase. XRD and HRTEM characterization after\n reaction revealed that on Cu/SiO2 significant sintering occurred during\n reaction. In contrast, the particle size growth on Cu/TiO2 rutile and\n anatase was less pronounced, which could be associated with the\n interaction between Cu clusters and TiO2. Characterization by TGA showed\n that on Cu/Al2O3-SiO2 the main cause of deactivation was coke\n deposition. |
| Keywords |
Alumina; Aluminum oxide; Catalysts; Methanol; Oxide minerals; Particle size; Silica; Sintering; Steam reforming; Titanium dioxide; Coke deposition; Copper catalyzed; Metal oxides; Methanol reforming; |
| Universidad Loyola members |
|
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