Title The Oxy-CaL process: A novel CO2 capture system by integrating partial oxy-combustion with the Calcium-Looping process
Authors ORTIZ DOMÍNGUEZ, CARLOS, Valverde, J. M. , Chacartegui, R. , Benitez-Guerrero, M. , Perejon, A. , Romeo, L. M.
External publication Si
Means Appl. Energy
Scope Article
Nature Científica
JCR Quartile 1
SJR Quartile 1
JCR Impact 7.90000
SJR Impact 3.16200
Publication date 15/06/2017
ISI 000401048000001
DOI 10.1016/j.apenergy.2017.03.120
Abstract This paper proposes a novel CO2 capture technology from the integration of partial oxy-combustion and the Calcium -Looping capture process based on the multicycle carbonation/calcination of limestone derived CaO. The concentration of CO2 in the carbonator reactor is increased by means of partial oxycombustion, which enhances the multicycle CaO conversion according to thermogravimetric analysis results carried out in our work, thus improving the CO2 capture efficiency. On the other hand, energy consumption for partial oxy-combustion is substantially reduced as compared to total oxy-combustion. All in all, process simulations indicate that the integration of both processes has potential advantages mainly regarding power plant flexibility whereas the overall energy penalty is not increased. Thus, the resulting energy consumption per kilogram of CO2 avoided is kept smaller than 4 MI/kg CO2, which remains below the typical values reported for total oxy-combustion and amine based CO2 capture systems whereas CO2 capture efficiency is enhanced in comparison with the Calcium -Looping process. (C) 2017 Elsevier Ltd. All rights reserved.
Keywords Calcium-Looping; Oxy-combustion; CCS; SPECCA
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